- Department of Chemistry, IIT Hyderabad
- +91 (40) 2301 6015
- office@chy.iith.ac.in
Stereochemistry,prostereoisomerism, nomenclature of stereotopic ligands and faces, stereoheterotopic ligands and NMR spectroscopy.Conformational analysis; Stereoselectivity. Circular dichroism, ORD, cotton effect, application of ORD and CD in steriods, examples illustrating the usefulness of Cotton effect. Reaction mechanisms, Basic mechanistic concepts. Nucleophilic substitution, Rearrangement reactions.
Periodicity in Properties, Chemical Bonding, geometry and shape of simple molecules.Introduction to Transition Elements, Introduction to Coordination compounds, Isolation of Metals, Chemical principles and reactions of extractive metallurgy.
Basic electrochemistry , Debye-Huckel theory, Debye-Huckel-Onsager equation, ion transport in solution, Fick’s laws of diffusion, ion-solvent interactions, ion-ion interactions, electrode-electrolyte interface phenomena, Guoy-Chapman and Stern models, polarization and overpotential, Butler-Volmer Equation, systems of technological interest.
X-ray diffraction, principles of inorganic crystal structures, crystal chemistry and bonding in solids; preparative methods, characterization of inorganic solids: application of physical techniques, thermal analysis, electronic properties and band theory.
Introduction,Postulates, Schrödinger equation: wave function and interpretation, time dependent and time independent Schrödinger equation, eigenvalue problem. Quantum mechanics of some simple systems,Hydrogen and hydrogen like atoms, Approximate methods,Many electron atom,Vibrational and Rotational spectroscopy.
Advanced Organic Chemistry Practicals.
Advanced Inorganic Chemistry Practicals.
Alkenes and alkynes synthesis; Alkenes and alkynes applications; Pericyclic reactions; Carbonyl compounds.
Detail knowledge about the coorination compounds, organometallic compounds and reaction mechanism involving these compounds.
Surface Science: Jablonski diagram, basics of fluorescence, phosphorescence,basics of
photochemistry , photochemical reactions , detail knowledge about LASER.
Types of statistics, Partition Functions,
Thermodynamics properties of monoatomic, diatomic gases, molar partition function of a system, partition function of
a real gas,Introduction to
Quantum statistical mechanics.
Review of basic principles of quantum theory, Born-Oppenheimer approximation, comparison of VB and MO theories. Hartree-Fock theory of atoms, Self Consistent Field (SCF) wavefunctions for diatomic molecules, configuration interaction(CI) wave functions, SCF-MO treatment of simple molecules, Koopmans theorems, huckel theory, Operations and symmetry elements, Applications to molecular orbital theory and spectroscopy, Character tables and symmetry,selection rules.
Nuclear Magnetic Resonance Spectroscopy,13C-NMR, Introduction to FT technique, Introduction to 31P and 19F NMR. Infrared and Raman spectroscopy. Mass spectrometry. Electronic spectroscopy.
Advanced Physical Chemistry Practicals
Will update soon
Metal ions in biology. heme and non-heme systems, Peptide and nucleotide, electronic, magnetic and redox properties;fixation of N2, water-oxidation reactions,syntheses of ligand-metal complexes, high-valent metal-oxo systems, Interaction of metal ions with nucleotides and peptides, hydrolysis of phosphate and amide groups, Metal based drugs, environmental applications and toxic effects.
Rotational spectroscopy, Vibrational Spectroscopy, Vibrational-Rotational spectra. Raman spectroscopy, electrical and magnetic properties of molecules, NMR, FT-NMR, Relaxation processes in NMR, ESR spectroscopy, Kramers degeneracy, Mossbauer spectroscopy.
LIST OF ELECTIVE SUBJECTS IS GIVEN ALONG WITH PHD COURSES.
Research project with a Thesis, where a student works (experimental or theoretical) on a topic from Organic or Inorganic or Physical Chemistry.
LIST OF ELECTIVE SUBJECTS IS GIVEN ALONG WITH PHD COURSES.
LIST OF ELECTIVE SUBJECTS IS GIVEN ALONG WITH PHD COURSES.
Research project with a Thesis, where a student works (experimental or theoretical) on a topic from Organic or Inorganic or Physical Chemistry.